In this paper the recent progress on applications of nano transition metal catalysts in organic synthetic chemistry is reviewed , and an outlook of their developments is also discussed 綜述了近年來(lái)納米級(jí)過(guò)渡金屬催化劑在有機(jī)合成方面的應(yīng)用,并對(duì)其發(fā)展作了展望。
The behavior of 1 , 6 - enyne in the presence of transition metal catalysts had been extensively studied . 1 , 6 - enyne cycloisomerization reactions catalyzed by transition metals and three different reaction pathways , namely cyclometalation , halorhodation and - allyl rhodium route , divided according to the reaction mechanism are summarized and discussed 摘要1 , 6 -烯炔底物在過(guò)渡金屬催化劑作用下的化學(xué)行為得到了廣泛的研究,重點(diǎn)是關(guān)于過(guò)渡金屬催化的1 , 6 -烯炔環(huán)異構(gòu)化反應(yīng),從反應(yīng)機(jī)理角度入手,把1 , 6 -烯炔環(huán)異構(gòu)化反應(yīng)按啟動(dòng)方式總結(jié)為三類(lèi),關(guān)對(duì)這三種方式啟動(dòng)的1 , 6 -烯炔構(gòu)化應(yīng)進(jìn)行了詳細(xì)地總結(jié)和闡述。